All very nice (though the part about powering a developing nation sounds like junk because, as Photon has pointed out, the Laws of Thermodynamics do not make sense with the described values of effectiveness (more on this at the end)), but this also raises multiple issues. First is the ability to capture and separate the gas (which I could imagine would be done by absorbing the oxygen onto something). The second, much more minor, issue that I know of off the top of my head is oxygen pollution. Oxygen at higher concentrations is more deadly (and gives lead to damages from free radicals).
On the topic of thermodynamic failures, let's say it COULD be 100% efficient with energy (IE the energy you put in is the energy you'll get out...an impossibility given the two laws of thermodynamics, as nothing can be =<100% efficient):
- Given Photon's calculations, I get 2.3086 watts of power out of the card sized leaf.
- That means that you can vapourize 8.077*10-6 moles per second, giving you 8.077*10^-6 moles of hydrogen every second.
Assuming 24 hour permanoon type of conditions, that gives .697838 moles of hydrogen to work with (as oxygen is pretty useless here).
- The combustion enthalpy of hydrogen is -288 kJ/mol (where the extra energy comes from is the ignition source. Pretend it doesn't matter

), or yields 200977 J of energy.
Given these values:
http://www.absak.com/library/power-consumption-table ... (assuming you let these things build you hydrogen all day):
- 2 of them will run an electric clock non-stop (until you need to replace the leaf)
- 205 will keep you food in the fridge
- 2 charging all day will let you watch a short sports game on a 12" black and white TV
- 306 will be needed to let a pair of brothers with a sander and saw build a house on a standard 8 hour day.
- 4 charging all day could give dad his morning cup of joe, toast, and keep him nice and shaved for the work day
- ~2150 will keep a small 5 room apartment cool
While some don't seem too bad, remember that these are assuming permanent lighting conditions AND requires the full day of energy to fuel the short events.
Seems a little impractical still...but I don't mind where it's heading.