NVTCP.sys looks like a network card driver for the nForce nvidia chipset.
Check the nvidia website for the latest nforce drivers for your chipset, you might have to check your motherboard model to figure out if it's nforce2, 3, 4, etc..
Could also be related to that nvidia firewall software if you've got that installed.
Could also be an actual hardware problem with the network chip, though that's unlikely. Barring anything else you can try disabling it in BIOS and using a different network card.
Does this happen on every bootup? Or just at random intervals? Or on heavy use (bittorrent)?
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But certainty is an absurd one.
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