Battery life is rated to be better on the S5 along with having water and dust proofing.
That's being said, the S6 is superior is every other way if that matters (which might not given a bigger price tag) including camera, screen quality, internal hardware.
Oh and if storage size matters, the S6 and its edge variant come in base 32GB, none expandable with the S5 being 16GB with expandable storage.
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