I believe that the events that happen in IronMan 3 and Thor 2 are happening at the exact same time as Cap 2.
Which would occupy Tony Stark and Thor, Black Widow is with Cap and apparently in Avengers 2 they will reveal why Hulk and Hawkeye were busy as well.
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"In brightest day, in blackest night / No evil shall escape my sight / Let those who worship evil's might / Beware my power, Green Lantern's light!"
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