Bayern are actually the favourites to win the Champions League, not Barcelona, so yes, you should definitely take them if the guy with the first pick takes Barca.
1 Bayern Munich
2 Barcelona
3 Real Madrid
4 Chelsea
5 Manchester United
6 Manchester City
7 Juventus
8 PSG
9 Borussia Dortmund
10 Arsenal
11 Napoli
12 AC Milan
sites like pinnacle and betfair are a great way to research stuff like this
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