Did he have "Find my iPhone" enabled?
If he did he can go to icloud.com, log in with the apple ID associated with the phone, and you can find it through the web interface and even make it play a sound via the web interface.
A friend of mine in Toronto was worried that he left his iPhone at the cottage, a 3 hour trip out of town. He had looked all around the house... even tried calling it, but remembered he had left it on vibrate mode. He looked it up on my iPad and played the sound.. it had fallen out of his pocket and between the seat cushions on his sofa. Saved him from driving all the way to the cottage and getting frustrated that it wasn't there....
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