Gate 44 is on the other side of the airport though, if he is coming in on Air Canada and departing with Luftansa. He is going to have to exit A concourse, walk over to D concourse and go through security once again. Still enough time if his flight arrives on time, cutting it close if its delayed.
I didn't think Air Canada ran 2 Frankfurt flights a day, just the one which usually left later at night.
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