I use to have that issue as I live on a corner lot, I narrowed it down to 5 possible culprits but I never caught the person in the act. I got lucky and one of those 5 people moved away and all of a sudden no more dog poop and dog pee wrecking that portion of my lawn, the grass is finally starting to grow back that has been ruined.
Not much you can do, I've also heard, not sure if this is true that dogs don't go near human piss so you can piss in a jar and leave it out and the dog may refuse to go poop on your lawn.
The thing I was about to do was install a motion light near there, that way you could catch him in the act because when you are home you will most likely see the floodlight go on.
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