Human Torch hit the nail right on the head. There's nothing spectacular when it comes to RPGs on the PS3, yet. Valkyria Chronicles (if you can find it) is supposed to be amazing and Demon Souls is supposed to be great though it's expected release date is sometime in October. Another game called Tales of Vesperia has been announced for the PS3 (it's already out on the XBox) though I'm not sure if that's a worldwide release or Japan only. You should probably check that one out too as it's a pretty good JRPG.
Also, as Flash Walken stated, Fallout 3 is a great RPG and I believe in the next few weeks they will be releasing all the DLC packs (five in total) for the PS3.
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