What type of website are you creating? If it consists strictly of HTML/CSS files, Dreamweaver is probably the best software to start with.
It's also a good transition environment if you want to get into more dynamic sites that use PHP or another programming language.
Personally I have a huge loathing for anything WYSIWYG. It takes about as much time to make a site using straight mark up and CSS (includes learning the basics) as it does trying to massage a WYSIWYG editor into doing what you want.
I tend to use fancy "text-editors" (I'm a web developer).
On windows: PSPad or Notepad++ (also had fun using Visual Studio Web Developer as a straight HTML/CSS editor).
On Mac: Coda/Textmate (HTML scripts make things waaay easier).
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