I had no problems with what you noted when I made the switch. I won't say it'll be flawless because my sister in law owned one of the only printers in the world that wouldn't work on a mac, so it does happen. Anytime I've run into an issue at all google has pretty much dealt with it immediately.
Ask anything and everything you can. if there's something your windows machine did that you wish your mac would do, it probably already does it. There are a ton of little things that don't get talked about a whole lot (like how to take a screenshot and such).
I'd REALLY recommend heading into itunes and taking a look at the Apple Quick Tips podcast. Basically just a weekly video of a handy little trick you can do with your mac. There's a ton in there now and I've found a lot of cool things that nobody ever told me about (like how you can convert any web receipt from a web purchase instantly to a pdf and send it to a designated folder on your computer.)
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