If you're in Germany, I think you should definitely stop in Munich for at least some of that time like others have said. An amazing city with lots of history and a great vibe to it.
I would also recommend skipping Naples as well, unless there's something you really want to see there. When I was in Europe I thought about doing a day trip to Pompeii but instead went to Cinque Terre. It's an amazing place with 5 little picturesque villages scattered along a beautiful trail along the coast, about an hour or so from Rome. It's already becoming quite popular with tourists so I'd recommend getting there as it's still a great charming little area of Italy that not too many people know about!
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