I have thought long and hard about this one and I keep coming back to the scene in Boogie Nights where Alfred Molina is smoking crack and listening to Sister Christian and Jesse's Girl (on his "awesome mix tape #6"). The pacing, acting and music in that scene blended together so damn perfectly that I am just blown away every time I watch that flick. The shot where the camera stays on Mark Wahlberg for a minute is unforgettable. I am anxious to hear from you guys and gals and what your favourite scenes are.
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