I went down to Argentina, Uruguay, and Antarctica back in February. I just booked all the flights online to get down there. Air Canada to Buenos Aires, then searched online for the domestic flights in Argentina.
However if possible try to stay away from Aerolineas Argentinas, they are having a huge amount of financial and labour troubles. Flights get cancelled daily without notice and it could leave you high and dry. Stick with Lan Chile or Lan Argentina, a good company using good modern aircraft.
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