No, don't chill it. Sip it at room temp. There's no need to store it chilled therefore either. It will keep pretty much indefinitely at room temp. It's not like wine. Think of it more as whiskey, rum, vodka, etc. for storage purposes. As for the best type of glass, a brandy snifter if fine. It doesn't have to be a really big one though ... I prefer a smaller snifter.
And if you're a smoker, cigars go with cognac like white on rice.
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